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Issue 68, 2016
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Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

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Abstract

An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst. The process features a low-cost metal catalyst and atom economy, which provides an appealing strategy for future synthetic chemistry.

Graphical abstract: Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

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Publication details

The article was received on 16 May 2016, accepted on 18 Jul 2016 and first published on 18 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC04109D
Citation: Chem. Commun., 2016,52, 10407-10410
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    Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

    G. Zhang, L. Zhang, H. Yi, Y. Luo, X. Qi, C. Tung, L. Wu and A. Lei, Chem. Commun., 2016, 52, 10407
    DOI: 10.1039/C6CC04109D

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