Sulfur-centred polyoxoniobate-based 3D organic–inorganic hybrid compound and its magnetic behavior†
Abstract
The first sulfur-centered polyanion {SNb8V9.25O45.25} was isolated, which is covalently extended by cobalt complexes into a three-dimensional (3D) architecture. Moreover, the resulting 3D organic–inorganic hybrid compound orders as a weak ferromagnet at low temperature.