Issue 68, 2016

Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

Abstract

One-dimensional polymer chains consisting of π-conjugated porphyrin units are formed via Glaser coupling on a Ag(111) surface. Scanning probe microscopy reveals the covalent structure of the products and their ordering. The conformational flexibility within the chains is investigated via a comparision of room temperature and cryogenic measurements.

Graphical abstract: Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

Supplementary files

Article information

Article type
Communication
Submitted
04 May 2016
Accepted
19 Jun 2016
First published
20 Jun 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 10342-10345

Author version available

Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

A. Saywell, A. S. Browning, P. Rahe, H. L. Anderson and P. H. Beton, Chem. Commun., 2016, 52, 10342 DOI: 10.1039/C6CC03758E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements