The size-dependent recognition of large anions by shape-persistent macrocycles is poorly understood. To address this shortcoming, we created a bulky cyanostar that only forms 1 : 1 complexes and show the affinities best follow the expectations of size matching but only when solvent bias is removed.
B. Qiao, Joseph. R. Anderson, M. Pink and A. H. Flood, Chem. Commun., 2016, 52, 8683 DOI: 10.1039/C6CC03463B
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