Issue 49, 2016
From the journal:

Chemical Communications

A stepwise bulk-to-cluster-to-particle transformation toward the efficient synthesis of alkynyl-protected silver nanoclusters†

Hui Guo,ab   Xin He,b   Chong-Qing Wan*a  and  Liang Zhao*b  

* Corresponding authors

a Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, China
E-mail: wancq@cnu.edu.cn

b Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: zhaolchem@mail.tsinghua.edu.cn

Abstract

We report herein the efficient synthesis of alkynyl-protected silver nanoclusters in terms of macrocycle-assisted bulk-to-cluster-to-nanoparticle transformation. Different substituted phenylacetylide ligands are applied to stabilize the silver nanoclusters by metal–carbon bonds and meanwhile determine the size of silver nanoclusters.

Graphical abstract: A stepwise bulk-to-cluster-to-particle transformation toward the efficient synthesis of alkynyl-protected silver nanoclusters

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Article information

DOI
https://doi.org/10.1039/C6CC02950G
Article type
Communication
Submitted
08 Apr 2016
Accepted
23 May 2016
First published
23 May 2016

Chem. Commun., 2016,52, 7723-7726

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A stepwise bulk-to-cluster-to-particle transformation toward the efficient synthesis of alkynyl-protected silver nanoclusters

H. Guo, X. He, C. Wan and L. Zhao, Chem. Commun., 2016, 52, 7723 DOI: 10.1039/C6CC02950G

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