Issue 44, 2016
From the journal:

Chemical Communications

The first synthesis and X-ray crystallographic analysis of an oxygen-bridged planarized triphenylborane†

Yuichi Kitamoto,*a   Takatsugu Suzuki,b   Yasuo Miyata,b   Hiroshi Kita,c   Kenji Funakid  and  Shuichi Oi*a  

* Corresponding authors

a New Industry Creation Hatchery Center, Tohoku University, 6-6-11 Aramaki-Aoba, Aoba-ku, Sendai 980-8579, Japan
E-mail: kitamoto@orgsynth.che.tohoku.ac.jp, oishu@aporg.che.tohoku.ac.jp

b Technology Research Group, Advanced Technology Center, Corporate R&D Headquarters, Konica Minolta, Inc., 2970 Ishikawa-Machi, Hachioji-shi, Tokyo 192-8505, Japan

c Organic Materials Laboratories, Advanced Layers Business Unit, Konica Minolta, Inc., 2970 Ishikawa-Machi, Hachioji-shi, Tokyo 192-8505, Japan

d Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, 6-6-11 Aramaki-Aoba, Aoba-ku, Sendai 980-8579, Japan

Abstract

An oxygen-bridged planarized triphenylborane has been successfully synthesized. X-ray crystallographic analysis revealed that the molecule has a complete planarized structure and the shortest C–B bonds among the triarylboranes synthesized to date.

Graphical abstract: The first synthesis and X-ray crystallographic analysis of an oxygen-bridged planarized triphenylborane

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Article information

DOI
https://doi.org/10.1039/C6CC02440H
Article type
Communication
Submitted
21 Mar 2016
Accepted
29 Apr 2016
First published
29 Apr 2016

Chem. Commun., 2016,52, 7098-7101

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The first synthesis and X-ray crystallographic analysis of an oxygen-bridged planarized triphenylborane

Y. Kitamoto, T. Suzuki, Y. Miyata, H. Kita, K. Funaki and S. Oi, Chem. Commun., 2016, 52, 7098 DOI: 10.1039/C6CC02440H

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