Issue 46, 2016
From the journal:

Chemical Communications

The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes†

Nicole S. Y. Loy,a   Subin Choi,b   Sunggak Kima  and  Cheol-Min Park*b  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore

b Department of Chemistry, UNIST (Ulsan National Institute of Science & Technology), Ulsan 44919, Korea
E-mail: cmpark@unist.ac.kr

Abstract

Cationic gold complexes of α-oximimino carbenes have been identified to react with weak nucleophiles including enol ethers and nitriles. These findings allowed us to develop the highly efficient synthesis of pyrroles and oxazoles.

Graphical abstract: The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes

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Article information

DOI
https://doi.org/10.1039/C6CC01742H
Article type
Communication
Submitted
26 Feb 2016
Accepted
25 Apr 2016
First published
25 Apr 2016

Chem. Commun., 2016,52, 7336-7339

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The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes

N. S. Y. Loy, S. Choi, S. Kim and C. Park, Chem. Commun., 2016, 52, 7336 DOI: 10.1039/C6CC01742H

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