Issue 28, 2016
From the journal:

Chemical Communications

Bi(iii) polybromides: a new chapter in coordination chemistry of bismuth†

Sergey A. Adonin,*ab   Igor D. Gorokh,ab   Denis G. Samsonenko,ab   Maxim N. Sokolovab  and  Vladimir P. Fedinab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, 630090 Novosibirsk, Russia
E-mail: adonin@niic.nsc.ru

b Novosibirsk State University, Pirogova St. 2, 630090 Novosibirsk, Russia

Abstract

A new family of bismuth coordination compounds – Bi(III) polybromides – is introduced. Four representatives of this class – (N-EtPy)3[Bi2Br9](Br2)2 (1), (4-MePyH)3[Bi2Br9](Br2) (2), (H2bpe){[BiBr5]}(Br2) (3) and (BPB)2[BiBr5(Br3)](Br3)(Br2) (4) – were obtained in a simple way from HBr solutions of BiBr3 with added Br2, highlighting the diversity of the structural types in the new family of complexes.

Graphical abstract: Bi(iii) polybromides: a new chapter in coordination chemistry of bismuth

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Article information

DOI
https://doi.org/10.1039/C6CC01704E
Article type
Communication
Submitted
25 Feb 2016
Accepted
10 Mar 2016
First published
10 Mar 2016

Chem. Commun., 2016,52, 5061-5063

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Bi(III) polybromides: a new chapter in coordination chemistry of bismuth

S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, M. N. Sokolov and V. P. Fedin, Chem. Commun., 2016, 52, 5061 DOI: 10.1039/C6CC01704E

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