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Issue 45, 2016
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Tetrahedral cage complex with planar vertices: selective synthesis of Pt4L6 cage complexes involving hydrogen bonds driven by halide binding

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Abstract

The reaction of Fe(η-C5H4NHC(O)PPh2)2 (L) with PtX2(PPh3)2 selectively formed cage-shaped complexes formulated as [(PtX)4(L)6]X4·CHCl3 (X = Cl, Br), in which the four square-planar Pt fragments were situated at each vertex and the six Ls were located in each side of a tetrahedral framework and hydrogen bonds existed between the NH groups in Ls and X ions inside the cage.

Graphical abstract: Tetrahedral cage complex with planar vertices: selective synthesis of Pt4L6 cage complexes involving hydrogen bonds driven by halide binding

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Publication details

The article was received on 17 Feb 2016, accepted on 21 Apr 2016 and first published on 22 Apr 2016


Article type: Communication
DOI: 10.1039/C6CC01448H
Citation: Chem. Commun., 2016,52, 7205-7208
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    Tetrahedral cage complex with planar vertices: selective synthesis of Pt4L6 cage complexes involving hydrogen bonds driven by halide binding

    M. Ito, M. Iseki, M. Itazaki and H. Nakazawa, Chem. Commun., 2016, 52, 7205
    DOI: 10.1039/C6CC01448H

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