We have successfully achieved the stereoselective synthesis of a specific cis-diene moiety through a dehalogenative homocoupling of alkenyl bromides on the Cu(110) surface, where the formation of a cis-form organometallic intermediate is the key to such a stereoselectivity as determined by DFT calculations.
Q. Sun, L. Cai, H. Ma, C. Yuan and W. Xu, Chem. Commun., 2016, 52, 6009 DOI: 10.1039/C6CC01059H
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