Issue 30, 2016
From the journal:

Chemical Communications

Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions†

D. J. Blair,‡a   S. Zhong,‡a   M. J. Hesse,a   N. Zabaleta,a   E. L. Myersa  and  V. K. Aggarwal*a  

* Corresponding authors

a School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK
E-mail: v.aggarwal@bristol.ac.uk
Fax: +44 (0)117 929 8611
Tel: +44 (0)117 954 6315

Abstract

Hindered tertiary neopentyl glycol boronic esters can be prepared by using in situ lithiation–borylation of enantiopure secondary benzylic carbamates at −20 °C with full chirality transfer.

Graphical abstract: Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

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Article information

DOI
https://doi.org/10.1039/C6CC00536E
Article type
Communication
Submitted
19 Jan 2016
Accepted
14 Mar 2016
First published
22 Mar 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 5289-5292

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Full chirality transfer in the synthesis of hindered tertiary boronic esters under in situ lithiation–borylation conditions

D. J. Blair, S. Zhong, M. J. Hesse, N. Zabaleta, E. L. Myers and V. K. Aggarwal, Chem. Commun., 2016, 52, 5289 DOI: 10.1039/C6CC00536E

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