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Issue 58, 2016
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Directly linked hydroporphyrin dimers

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Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded mesomeso-linked homo- and heterodimers, and meso-β-linked dimers. The photophysical and electrochemical properties of the dimers are reported.

Graphical abstract: Directly linked hydroporphyrin dimers

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The article was received on 18 Jan 2016, accepted on 03 Feb 2016 and first published on 03 Feb 2016

Article type: Communication
DOI: 10.1039/C6CC00516K
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2016,52, 9056-9058
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    Directly linked hydroporphyrin dimers

    R. Xiong, A. I. Arkhypchuk, D. Kovacs, A. Orthaber and K. Eszter Borbas, Chem. Commun., 2016, 52, 9056
    DOI: 10.1039/C6CC00516K

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