Issue 14, 2016
From the journal:

Chemical Communications

A self-assembled, multicomponent water oxidation device†

Rita Tóth,a   Roché M. Walliser,b   Niamh S. Murray,b   Debajeet K. Bora,a   Artur Braun, ORCID logo a   Guiseppino Fortunato,c   Catherine E. Housecroftb  and  Edwin C. Constable*b  

* Corresponding authors

a Laboratory for High Performance Ceramics, Empa. Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, Dubendorf, Switzerland

b Department of Chemistry, University of Basel, Spitalstrasse 51, CH4056 Basel, Switzerland
E-mail: edwin.constable@unibas.ch

c Protection and Physiology, Empa, Swiss Federal Laboratories for Materials Science and Technology, Lerchenfeldstr. 5, 9014 St. Gallen, Switzerland

Abstract

Langmuir–Blodgett (LB) and drop-cast (DC) films prepared from [Ru(1)3][PF6]2 and Co4POM (1 = 4,4′-bis(nnonyl)-2,2′-bipyridine, Co4POM = K10[Co4(H2O)2(α-PW9O34)2]) have been evaluated as water oxidation catalysts and their electrocatalytic performances are reported; DC films evolve more O2 per unit area than LB films and the catalyst is stable on an FTO surface for ≈500–600 minutes.

Graphical abstract: A self-assembled, multicomponent water oxidation device

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Article information

DOI
https://doi.org/10.1039/C5CC09556E
Article type
Communication
Submitted
18 Nov 2015
Accepted
13 Jan 2016
First published
18 Jan 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 2940-2943

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A self-assembled, multicomponent water oxidation device

R. Tóth, R. M. Walliser, N. S. Murray, D. K. Bora, A. Braun, G. Fortunato, C. E. Housecroft and E. C. Constable, Chem. Commun., 2016, 52, 2940 DOI: 10.1039/C5CC09556E

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