Issue 13, 2016
From the journal:

Chemical Communications

TBAI-catalyzed oxidative C–H functionalization: a new route to benzo[b]phosphole oxides†

Yun Zhang,a   Gaobo Hu,a   Dumei Ma,b   Pengxiang Xu,a   Yuxing Gao*a  and  Yufen Zhaoa  

* Corresponding authors

a Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
E-mail: gaoxingchem@xmu.edu.cn

b Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Abstract

The first metal-free, efficient TBAI-catalyzed radical addition/cyclization of diaryl(arylethynyl)phosphine oxides with toluene derivatives has been developed, affording a general, one-step approach to structurally sophisticated benzo[b]phosphole oxides via sequential C–H functionalization along with the formation of two new C–C bonds.

Graphical abstract: TBAI-catalyzed oxidative C–H functionalization: a new route to benzo[b]phosphole oxides

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Article information

DOI
https://doi.org/10.1039/C5CC09263A
Article type
Communication
Submitted
09 Nov 2015
Accepted
28 Dec 2015
First published
05 Jan 2016

Chem. Commun., 2016,52, 2815-2818

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TBAI-catalyzed oxidative C–H functionalization: a new route to benzo[b]phosphole oxides

Y. Zhang, G. Hu, D. Ma, P. Xu, Y. Gao and Y. Zhao, Chem. Commun., 2016, 52, 2815 DOI: 10.1039/C5CC09263A

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