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Issue 15, 2016
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Phosphorescent columnar hybrid materials containing polyionic inorganic nanoclusters

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Abstract

The ternary polyionic inorganic compound Cs2Mo6Br14 and 18-crown-6 ethers bearing two o-terphenyl units have been combined to design phosphorescent columnar liquid crystalline hybrid materials. The obtained host–guest complexes are very stable even at high temperatures. Depending on their surrounding atmosphere, these hybrids switch reversibly from a high-to-low luminescence state and show a very stable emission intensity up to 140 °C.

Graphical abstract: Phosphorescent columnar hybrid materials containing polyionic inorganic nanoclusters

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Publication details

The article was received on 03 Nov 2015, accepted on 06 Jan 2016 and first published on 06 Jan 2016


Article type: Communication
DOI: 10.1039/C5CC09110A
Citation: Chem. Commun., 2016,52, 3127-3130
  • Open access: Creative Commons BY license
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    Phosphorescent columnar hybrid materials containing polyionic inorganic nanoclusters

    S. K. Nayak, M. Amela-Cortes, M. M. Neidhardt, S. Beardsworth, J. Kirres, M. Mansueto, S. Cordier, S. Laschat and Y. Molard, Chem. Commun., 2016, 52, 3127
    DOI: 10.1039/C5CC09110A

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