Issue 5, 2016

Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers

Abstract

We designed a planar chiral two-layered cyclophane, which is inherently achiral but desymmetrized by the arrangement of two nonstereogenic centers. We demonstrate the control of dynamic helicity that is generated by the helical twisting of two-layered planes in the cyclophane, where methyl and cyclohexylmethyl groups act as directing groups.

Graphical abstract: Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers

Supplementary files

Article information

Article type
Communication
Submitted
02 Nov 2015
Accepted
14 Nov 2015
First published
17 Nov 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 1029-1031

Author version available

Planar chiral desymmetrization of a two-layered cyclophane and control of dynamic helicity through the arrangement of two nonstereogenic centers

R. Katoono and T. Suzuki, Chem. Commun., 2016, 52, 1029 DOI: 10.1039/C5CC09069E

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