Issue 7, 2016
From the journal:

Chemical Communications

Aluminum oxide mediated C–F bond activation in trifluoromethylated arenes†

O. Papaianinaa  and  K. Yu. Amsharov*a  

* Corresponding authors

a Institute of Organic Chemistry II, University Erlangen-Nuernberg, Henkestr.42, 91054 Erlangen, Germany
E-mail: konstantin.amsharov@fau.de

Abstract

Thermally activated γ-aluminium oxide was found to be very effective for C–F bond activation in trifluoromethylated arenes. Depending on the activation degree the respective arenes can be converted either to cyclic ketones or to the respective carboxylic acids with good to excellent yields.

Graphical abstract: Aluminum oxide mediated C–F bond activation in trifluoromethylated arenes

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Article information

DOI
https://doi.org/10.1039/C5CC08747C
Article type
Communication
Submitted
21 Oct 2015
Accepted
24 Nov 2015
First published
25 Nov 2015

Chem. Commun., 2016,52, 1505-1508

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Aluminum oxide mediated C–F bond activation in trifluoromethylated arenes

O. Papaianina and K. Yu. Amsharov, Chem. Commun., 2016, 52, 1505 DOI: 10.1039/C5CC08747C

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