Jump to main content
Jump to site search

Issue 5, 2016
Previous Article Next Article

Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

Author affiliations

Abstract

We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2]23− (M = CoII or MnII), which contain {PW6} fragments generated from the [P2W15O56]12− precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry.

Graphical abstract: Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 13 Oct 2015, accepted on 06 Nov 2015 and first published on 09 Nov 2015


Article type: Communication
DOI: 10.1039/C5CC08486E
Citation: Chem. Commun., 2016,52, 919-921
  • Open access: Creative Commons BY license
  •   Request permissions

    Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

    M. Martin-Sabi, R. S. Winter, C. Lydon, J. M. Cameron, D. Long and L. Cronin, Chem. Commun., 2016, 52, 919
    DOI: 10.1039/C5CC08486E

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author