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Issue 38, 2015
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Large-area wet-chemical deposition of nanoporous tungstic silica coatings

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Abstract

We report on a facile procedure for synthesis of nanoporous coatings of tungstic silica through wet-chemical deposition and post-treatment of tungsten-doped potassium silicate solutions. The process relies on an aqueous washing and ion exchange step where dispersed potassium salt deposits are removed from a 150 nm silicate gel layer. Through an adjustment of the pH value of the washing agent within the solubility regime of a tungstic salt precursor, the tungsten content of the remaining nanostructured coating can be controlled. We propose this route as a universal approach for the deposition of large-area coatings of nanoporous silica with the potential for incorporating a broad variety of other dopant species. As for the present case, we observe, on the one hand, antireflective properties which enable the reduction of reflection losses from float glass by up to 3.7 percent points. On the other hand, the incorporation of nanoscale tungstic precipitates provides a lever for tailoring the coating hydrophilicity and, eventually, also surface acidity. This may provide a future route for combining optical performance with anti-fouling functionality.

Graphical abstract: Large-area wet-chemical deposition of nanoporous tungstic silica coatings

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Publication details

The article was received on 07 Jul 2015, accepted on 28 Aug 2015 and first published on 28 Aug 2015


Article type: Paper
DOI: 10.1039/C5TC02045J
Citation: J. Mater. Chem. C, 2015,3, 10031-10039
  • Open access: Creative Commons BY-NC license
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    Large-area wet-chemical deposition of nanoporous tungstic silica coatings

    K. H. Nielsen, K. Wondraczek, U. S. Schubert and L. Wondraczek, J. Mater. Chem. C, 2015, 3, 10031
    DOI: 10.1039/C5TC02045J

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