Linearly π-conjugated oligothiophenes as simple metal-free sensitizers for dye-sensitized solar cells

Abstract

Four linear oligothiophenes containing 4, 5 and 7 thiophene rings substituted by a variable number of octyl chains attached at the beta-position of some of the thiophene rings and possessing a terminal cyanoacrylic acid anchoring group have been synthesized. Results of UV-Vis absorption spectroscopy and cyclic voltammetry show that as expected the extension of the π-conjugated system leads to a decrease of the optical gap with an increase of the HOMO level. The four compounds have been evaluated as sensitizers in dye-sensitized solar cells (DSSCs) using a iodide/triiodide liquid electrolyte and the results are discussed in terms of the structure–property relationship with regard to the extension of the conjugated system and the number and position of the octyl side chains using N719 as the reference system. A power conversion efficiency of ∼7.30% corresponding to 90% of the value given by N719 under identical conditions has been obtained with one of the heptamers.