Anomalous nano-barrier effects of ultrathin molybdenum disulfide nanosheets for improving the flame retardance of polymer nanocomposites

Abstract

Polymer/graphene-analogous nanosheet composites have great potential for improving their physical and mechanical properties during the past few years. Herein, ultrathin molybdenum disulfide (MoS₂) nanosheets were simultaneously exfoliated and non-covalently modified by ultrasonication in an aqueous solution of chitosan. The chitosan-modified MoS₂ (CS-MoS₂) nanosheets were then transferred from the aqueous solution to tetrahydrofuran by a simple solvent-exchange method for the fabrication of epoxy (EP) nanocomposites. Transmission electron microscopy and scanning electron microscopy were performed to display the homogeneous dispersion of CS-MoS₂ in an EP matrix. On incorporating 2 wt% CS-MoS₂ into an EP matrix, EP nanocomposites exhibited reductions of up to 43.3% and 14.6% in peak heat-release rate and total heat release derived from cone calorimeters compared to those of neat EP, respectively. Moreover, toxic volatiles, such as hydrocarbons, aromatic compounds and CO, that escaped from the flaming EP nanocomposites were decreased compared to that of neat EP, demonstrating the higher smoke safety. Combined with the analyses of char residues and thermal stability of EP nanocomposites, the reduced fire hazards of EP nanocomposites could be attributed to the nano-barrier effects of MoS₂, which could effectively inhibit the release of combustible gas to support burning and restrain the effusion of volatile toxic substances that cause the majority of deaths in fires.