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Issue 1, 2015
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A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

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Abstract

Self-assembly of colloidal particles at liquid–liquid interfaces is a process with great potential for the creation of controlled structures, due to the trapping of the particles in the plane of the interface combined with their lateral mobility. Here we present a multiscale characterisation of the adsorption and interfacial behaviour of core–shell iron oxide–poly(ethylene glycol) nanoparticles at a water–n-decane interface using three complementary, in situ, methods, which span many different length scales. First, dynamic interfacial measurements are taken to follow the adsorption of particles from the bulk aqueous phase to the interface. The mechanical properties of the interface are then probed using micron-sized tracers in probe-particle tracking and nano-tracers in fluorescence correlation spectroscopy. The results show that the rate of particle adsorption to the interface scales with the square of bulk concentration, as predicted by a recent model. In addition, we show that despite full monolayers of nanoparticles forming, the interface remains unexpectedly fluid, with only a slowing of tracer particle mobility but no evidence of interface jamming as seen for hard nanoparticles. Our results illustrate that nanoparticles stabilised by soft, extended polymeric shells, display distinct features at fluid interfaces that can be harnessed for the fabrication of functional materials.

Graphical abstract: A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

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Publication details

The article was received on 24 Aug 2014, accepted on 27 Oct 2014 and first published on 27 Oct 2014


Article type: Paper
DOI: 10.1039/C4SM01881H
Citation: Soft Matter, 2015,11, 118-129
  • Open access: Creative Commons BY license
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    A multiscale approach to the adsorption of core–shell nanoparticles at fluid interfaces

    A. Nelson, D. Wang, K. Koynov and L. Isa, Soft Matter, 2015, 11, 118
    DOI: 10.1039/C4SM01881H

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