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Issue 8, 2015
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Profluorescent verdazyl radicals – synthesis and characterization

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Abstract

The synthesis and characterization of various 6-oxo-verdazyl radicals and their diamagnetic styryl radical trapping products are presented. It is shown that styryl radical trapping products derived from N-phenyl verdazyls show fluorescence whereas the N-methyl congeners are non-fluorescent. In the parent N-phenyl verdazyls fluorescence is fully quenched which renders these compounds highly valuable profluorescent radical probes.

Graphical abstract: Profluorescent verdazyl radicals – synthesis and characterization

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The article was received on 27 Feb 2015, accepted on 26 May 2015 and first published on 05 Jun 2015


Article type: Edge Article
DOI: 10.1039/C5SC00724K
Citation: Chem. Sci., 2015,6, 4712-4716
  • Open access: Creative Commons BY license
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    Profluorescent verdazyl radicals – synthesis and characterization

    D. Matuschek, S. Eusterwiemann, L. Stegemann, C. Doerenkamp, B. Wibbeling, C. G. Daniliuc, N. L. Doltsinis, C. A. Strassert, H. Eckert and A. Studer, Chem. Sci., 2015, 6, 4712
    DOI: 10.1039/C5SC00724K

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