A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo3O16][Re(CO)3]4}5− and its catalytic performance for CO2 cycloaddition reactions

Zhiyuan Huo; Jipeng Guo; Jingkun Lu; Qiaofei Xu; Pengtao Ma; Juan Zhao; Dongdi Zhang; Jingyang Niu; Jingping Wang

doi:10.1039/C5RA14201F

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A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo₃O₁₆][Re(CO)₃]₄}⁵⁻ and its catalytic performance for CO₂ cycloaddition reactions†

Zhiyuan Huo,^a Jipeng Guo,^a Jingkun Lu,^a Qiaofei Xu,^a Pengtao Ma,^a Juan Zhao,^a Dongdi Zhang,^a Jingyang Niu*^a and Jingping Wang*^a

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* Corresponding authors

^a Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China
E-mail: jyniu@henu.edu.cn, jpwang@henu.edu.cn
Fax: +86 371 23886876

Abstract

A nona-vacant Keggin-type tricarbonyl rhenium derivative [(NH₄)₅]{[PMo₃O₁₆][Re(CO)₃]₄}·1.5H₂O was obtained and characterized. Its frontier orbitals were computed by density functional theory (DFT) calculations. Furthermore, it could act as a Lewis acid catalyst and promote the conversion of CO₂ to cyclic carbonate under mild reaction conditions with pyrrolidinium bromide as a co-catalyst.

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Article information

DOI: https://doi.org/10.1039/C5RA14201F
Article type: Communication
Submitted: 24 Jul 2015
Accepted: 31 Jul 2015
First published: 31 Jul 2015

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RSC Adv., 2015,5, 69006-69009

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A nona-vacant Keggin-type tricarbonyl rhenium derivative {[PMo₃O₁₆][Re(CO)₃]₄}⁵⁻ and its catalytic performance for CO₂ cycloaddition reactions

Z. Huo, J. Guo, J. Lu, Q. Xu, P. Ma, J. Zhao, D. Zhang, J. Niu and J. Wang, RSC Adv., 2015, 5, 69006 DOI: 10.1039/C5RA14201F

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