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Issue 55, 2015
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Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

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Abstract

The unique properties of pentafluorophenyl vinyl sulfonate allow for a hitherto unmet feat to be realised; efficient and high yielding, metal-free, radical-based alkene hydroacylation employing aldehyde as limiting reagent. The optimised conditions are shown to work in good yields across a series of aldehydes, thus demonstrating the wide applicability of the developed protocol.

Graphical abstract: Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

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Publication details

The article was received on 06 May 2015, accepted on 12 May 2015 and first published on 12 May 2015


Article type: Communication
DOI: 10.1039/C5RA08353B
Citation: RSC Adv., 2015,5, 44423-44426
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    Pentafluorophenyl vinyl sulfonate enables efficient, metal-free, radical-based alkene hydroacylation with an aldehyde as a limiting reagent

    V. Chudasama, RSC Adv., 2015, 5, 44423
    DOI: 10.1039/C5RA08353B

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