Jump to main content
Jump to site search

Issue 14, 2015
Previous Article Next Article

The effect of surfactant type and concentration on the size and stability of microbubbles produced in a capillary embedded T-junction device

Author affiliations

Abstract

This work presents an investigation of the effect of various surfactants on microbubble formation, size and stability in a capillary embedded T-Junction microfluidic device. Four different surfactants were chosen. An anionic surfactant, sodium dodecyl sulfate (SDS), two non-ionic surfactants, polyoxyethylene sorbitan monopalmitate (Tween 40) and polyoxyethylene glycol 40 stearate (PEG 40), and a cationic surfactant, cetyltrimethyl ammonium bromide (CTAB). Each surfactant was added to 50 wt% aqueous glycerol solution at high concentration (above the critical micelle concentration) varying from 2 to 5 and 10 wt%. Static surface tension and contact angle were measured, as well as the viscosity of the solutions. While the value of surface tension did not significantly change with increasing surfactant concentration, other properties of the solutions (i.e. viscosity and contact angle) were affected. Microbubbles with sizes varying from 50 to 360 μm all with polydispersity index values of <2% were produced with this technique. The nonionic surfactants were found to produce smaller bubbles. This is likely to have been due to their higher adsorption on to the hydrophobic channel surface and hence increase in the thickness of the liquid film at the contact line between the three phases for approximately similar capillary numbers and viscosities. Bubble stability for all cases was evaluated by monitoring the change in average diameter with time. Microbubbles coated with PEG 40 were found to be the most stable, lasting for 150 days with a uniform size reduction of ∼1.5% as compared with SDS microbubbles lasting only for 30 min after collection.

Graphical abstract: The effect of surfactant type and concentration on the size and stability of microbubbles produced in a capillary embedded T-junction device

Back to tab navigation

Publication details

The article was received on 24 Nov 2014, accepted on 19 Dec 2014 and first published on 19 Dec 2014


Article type: Paper
DOI: 10.1039/C4RA15167D
Citation: RSC Adv., 2015,5, 10751-10762
  •   Request permissions

    The effect of surfactant type and concentration on the size and stability of microbubbles produced in a capillary embedded T-junction device

    M. Parhizkar, M. Edirisinghe and E. Stride, RSC Adv., 2015, 5, 10751
    DOI: 10.1039/C4RA15167D

Search articles by author

Spotlight

Advertisements