Issue 10, 2015

Metal-free direct difunctionalization of alkenes with I2O5 and P(O)–H compounds leading to β-iodophosphates

Abstract

A novel and efficient procedure for direct difunctionalization of alkenes with I2O5 and P(O)–H compounds has been developed under metal-free conditions. The present methodology produces a series of substituted β-iodophosphates in moderate to good yields with high regioselectivity and favorable functional group tolerance.

Graphical abstract: Metal-free direct difunctionalization of alkenes with I2O5 and P(O)–H compounds leading to β-iodophosphates

Supplementary files

Article information

Article type
Research Article
Submitted
01 Jul 2015
Accepted
05 Aug 2015
First published
06 Aug 2015

Org. Chem. Front., 2015,2, 1356-1360

Author version available

Metal-free direct difunctionalization of alkenes with I2O5 and P(O)–H compounds leading to β-iodophosphates

C. Liu, M. Zhu, W. Wei, D. Yang, H. Cui, X. Liu and H. Wang, Org. Chem. Front., 2015, 2, 1356 DOI: 10.1039/C5QO00208G

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