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Issue 10, 2015
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‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

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Abstract

A new family of isomorphous [Cu4Ln] clusters (LnIII = Gd, Tb, Dy) with a ‘propeller’-like topology was obtained from the use of naphthalene-2,3-diol in CuII/LnIII chemistry; all complexes are ferromagnetically-coupled and display either magnetocaloric properties or SMM behavior depending on the central Ln ion.

Graphical abstract: ‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

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Publication details

The article was received on 12 Aug 2015, accepted on 08 Sep 2015 and first published on 09 Sep 2015


Article type: Research Article
DOI: 10.1039/C5QI00146C
Citation: Inorg. Chem. Front., 2015,2, 945-948
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    ‘All three-in-one’: ferromagnetic interactions, single-molecule magnetism and magnetocaloric properties in a new family of [Cu4Ln] (LnIII = Gd, Tb, Dy) clusters

    P. Richardson, D. I. Alexandropoulos, L. Cunha-Silva, G. Lorusso, M. Evangelisti, J. Tang and T. C. Stamatatos, Inorg. Chem. Front., 2015, 2, 945
    DOI: 10.1039/C5QI00146C

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