Issue 3, 2015
From the journal:

Inorganic Chemistry Frontiers

8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes†

Zelin Sun,ab   Erlin Yue,b   Mengnan Qu,*a   Irina V. Oleynik,c   Ivan I. Oleynik,c   Kanshe Li,a   Tongling Liang,b   Wenjuan Zhangb  and  Wen-Hua Sun*b  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China

b Key laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: whsun@iccas.ac.cn

c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Pr. Lavrentjeva 9, Novosibirsk 630090, Russia

Abstract

Cycloalkyl-modified 8-arylimino-5,6,7-trihydroquinolylnickel pre-catalysts, activated with either MAO or Et2AlCl, are highly active for the polymerization of ethylene into branched polyethylene waxes with narrow polydispersity.

Graphical abstract: 8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

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Article information

DOI
https://doi.org/10.1039/C4QI00162A
Article type
Research Article
Submitted
15 Oct 2014
Accepted
08 Jan 2015
First published
12 Jan 2015

Inorg. Chem. Front., 2015,2, 223-227

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8-(2-Cycloalkylphenylimino)-5,6,7-trihydro-quinolylnickel halides: polymerizing ethylene to highly branched and lower molecular weight polyethylenes

Z. Sun, E. Yue, M. Qu, I. V. Oleynik, I. I. Oleynik, K. Li, T. Liang, W. Zhang and W. Sun, Inorg. Chem. Front., 2015, 2, 223 DOI: 10.1039/C4QI00162A

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