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Issue 44, 2015
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Toward a tunable synthetic [FeFe] hydrogenase mimic: single-chain nanoparticles functionalized with a single diiron cluster

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Abstract

We report two novel “clickable” [(μ-S2C2H4NR)Fe2(CO)6] complexes and their incorporation into single-chain nanoparticles. Variations in the characteristic iron–carbonyl stretching bands caused by the polymer scaffolds confirmed changes in the symmetry and electronics of the complexes. This represents the first SCNP-based model of a metalloenzyme bearing a single, bioinspired active site.

Graphical abstract: Toward a tunable synthetic [FeFe] hydrogenase mimic: single-chain nanoparticles functionalized with a single diiron cluster

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Publication details

The article was received on 29 Jul 2015, accepted on 08 Sep 2015 and first published on 10 Sep 2015


Article type: Communication
DOI: 10.1039/C5PY01196E
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Citation: Polym. Chem., 2015,6, 7646-7651
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    Toward a tunable synthetic [FeFe] hydrogenase mimic: single-chain nanoparticles functionalized with a single diiron cluster

    C. A. Tooley, S. Pazicni and E. B. Berda, Polym. Chem., 2015, 6, 7646
    DOI: 10.1039/C5PY01196E

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