Issue 41, 2015
From the journal:

Organic & Biomolecular Chemistry

Pd(OAc)2-catalysed regioselective alkoxylation of aryl (β-carbolin-1-yl)methanones via β-carboline directed ortho-C(sp2)–H activation of an aryl ring†‡

Shivalinga Kollea  and  Sanjay Batra*ab  

* Corresponding authors

a Medicinal and Process Chemistry Division, CSIR-Central Drug Research Institute, Sector 10, Jankipuram Extension, Sitapur Road, Lucknow-226031, UP, India
E-mail: batra_san@yahoo.co.uk, s_batra@cdri.res.in

b Academy for Scientific and Innovative Research, New Delhi-110025, India

Abstract

Synthesis of (2-alkoxyphenyl)(9H-pyrido[3,4-b]indol-1-yl)methanone via Pd(OAc)2-catalyzed regioselective alkoxylation of aryl (β-carbolin-1-yl) methanones employing β-carboline directed ortho-C(sp2)–H activation of an aryl ring under oxidative conditions is described.

Graphical abstract: Pd(OAc)2-catalysed regioselective alkoxylation of aryl (β-carbolin-1-yl)methanones via β-carboline directed ortho-C(sp2)–H activation of an aryl ring

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Article information

DOI
https://doi.org/10.1039/C5OB01500F
Article type
Paper
Submitted
21 Jul 2015
Accepted
20 Aug 2015
First published
20 Aug 2015

Org. Biomol. Chem., 2015,13, 10376-10385

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Pd(OAc)2-catalysed regioselective alkoxylation of aryl (β-carbolin-1-yl)methanones via β-carboline directed ortho-C(sp2)–H activation of an aryl ring

S. Kolle and S. Batra, Org. Biomol. Chem., 2015, 13, 10376 DOI: 10.1039/C5OB01500F

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