Issue 39, 2015
From the journal:

Organic & Biomolecular Chemistry

The molecular recognition controlled stereomutation cycle in a dynamic helical assembly†

Mohit Kumar,a   Madugula Drona Reddy,a   Ananya Mishraa  and  Subi J. George*a  

* Corresponding authors

a Supramolecular Chemistry Laboratory, New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore, India
E-mail: george@jncasr.ac.in
Fax: +91 80 22082760
Tel: +91 80 22082964

Abstract

Perylene bisimide functionalized with a phosphate recognition unit assembles into a left-handed, right-handed or racemic helical assembly on binding with AMP, ATP and inorganic phosphates, respectively. Thus, competitive binding among these multivalent guests was utilized for completing an unprecedented helix mutation cycle in a dynamic supramolecular assembly.

Graphical abstract: The molecular recognition controlled stereomutation cycle in a dynamic helical assembly

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Article information

DOI
https://doi.org/10.1039/C5OB01448D
Article type
Communication
Submitted
15 Jul 2015
Accepted
25 Aug 2015
First published
25 Aug 2015

Org. Biomol. Chem., 2015,13, 9938-9942

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The molecular recognition controlled stereomutation cycle in a dynamic helical assembly

M. Kumar, M. D. Reddy, A. Mishra and S. J. George, Org. Biomol. Chem., 2015, 13, 9938 DOI: 10.1039/C5OB01448D

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