Jump to main content
Jump to site search

Issue 34, 2015
Previous Article Next Article

Palladium-catalyzed direct ortho-ethoxycarbonylation of azobenzenes and azoxybenzenes with diethyl azodicarboxylate

Author affiliations

Abstract

A palladium-catalyzed direct ortho-ethoxycarbonylation of azobenzenes and azoxybenzenes with diethyl azodicarboxylate (DEAD) was developed. In the presence of Cu(OAc)2 or (NH4)2S2O8 as the oxidant, this protocol allowed using both electron-deficient and electron-rich azobenzenes and azoxybenzenes to produce the corresponding products in moderate to good yields.

Graphical abstract: Palladium-catalyzed direct ortho-ethoxycarbonylation of azobenzenes and azoxybenzenes with diethyl azodicarboxylate

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Jun 2015, accepted on 15 Jul 2015 and first published on 17 Jul 2015


Article type: Paper
DOI: 10.1039/C5OB01264C
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2015,13, 9083-9092
  •   Request permissions

    Palladium-catalyzed direct ortho-ethoxycarbonylation of azobenzenes and azoxybenzenes with diethyl azodicarboxylate

    N. Xu, D. Li, Y. Zhang and L. Wang, Org. Biomol. Chem., 2015, 13, 9083
    DOI: 10.1039/C5OB01264C

Search articles by author

Spotlight

Advertisements