Issue 8, 2015
From the journal:

Organic & Biomolecular Chemistry

Pd-catalyzed benzylic C–H oxidation of cyclotriveratrylene – product diversity†

B. Senthilkumar,a   R. G. Gonnadeb  and  C. V. Ramana*a  

* Corresponding authors

a Division of Organic Chemistry, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India
E-mail: vr.chepuri@ncl.res.in
Fax: +91 20 2590 2629
Tel: +91 20 2590 2577

b Center for Material Characterization, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune-411008, India

Abstract

The inner-rim functionalization of CTV has been examined by employing Pd-catalyzed benzylic oxidation. The outcome of the oxidation depends upon the solvent and co-oxidants employed. An interesting array of CTV derivatives has been synthesized with a simple change in the conditions.

Graphical abstract: Pd-catalyzed benzylic C–H oxidation of cyclotriveratrylene – product diversity

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Article information

DOI
https://doi.org/10.1039/C4OB02469A
Article type
Paper
Submitted
24 Nov 2014
Accepted
15 Dec 2014
First published
15 Dec 2014

Org. Biomol. Chem., 2015,13, 2323-2329

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Pd-catalyzed benzylic C–H oxidation of cyclotriveratrylene – product diversity

B. Senthilkumar, R. G. Gonnade and C. V. Ramana, Org. Biomol. Chem., 2015, 13, 2323 DOI: 10.1039/C4OB02469A

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