Issue 6, 2015

A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

Abstract

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Graphical abstract: A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

Article information

Article type
Paper
Submitted
10 Nov 2014
Accepted
02 Dec 2014
First published
02 Dec 2014

Org. Biomol. Chem., 2015,13, 1768-1777

Author version available

A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

M. V. Rojo, L. Guetzoyan and Ian. R. Baxendale, Org. Biomol. Chem., 2015, 13, 1768 DOI: 10.1039/C4OB02376E

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