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Issue 6, 2015
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A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

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Abstract

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Graphical abstract: A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

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Publication details

The article was received on 10 Nov 2014, accepted on 02 Dec 2014 and first published on 02 Dec 2014


Article type: Paper
DOI: 10.1039/C4OB02376E
Citation: Org. Biomol. Chem., 2015,13, 1768-1777
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    A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions

    M. V. Rojo, L. Guetzoyan and Ian. R. Baxendale, Org. Biomol. Chem., 2015, 13, 1768
    DOI: 10.1039/C4OB02376E

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