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Issue 46, 2015
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Atom precise platinum–thiol crowns

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Abstract

Ligand stabilized water soluble Pt nanoclusters were synthesized and characterized through electrospray ionization mass spectrometry. Glutathione was used as the ligand, and Pt5(SG)10, and Pt6(SG)12 clusters were synthesized. Theoretical investigations found that these clusters do not possess a metal core, but rather are most stable in a ring structure. The clusters are stabilized through the thiol ligands forming a square planar structure around each Pt atom to form a ring. The structural elucidation was confirmed through UV/Vis and IR spectroscopy.

Graphical abstract: Atom precise platinum–thiol crowns

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The article was received on 06 Aug 2015, accepted on 05 Oct 2015 and first published on 08 Oct 2015


Article type: Paper
DOI: 10.1039/C5NR05325K
Author version available: Download Author version (PDF)
Citation: Nanoscale, 2015,7, 19448-19452
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    Atom precise platinum–thiol crowns

    A. George, K. S. Asha, A. C. Reber, S. R. Biltek, A. F. Pedicini, A. Sen, S. N. Khanna and S. Mandal, Nanoscale, 2015, 7, 19448
    DOI: 10.1039/C5NR05325K

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