Issue 3, 2015
From the journal:

New Journal of Chemistry

A ternary Rh complex catalyst highly active and stable in the hydrogenation of acrylonitrile–butadiene rubber†

Peng Cao,a   Meng Wu,a   Rui Zou,a   Liqun Zhangab  and  Dongmei Yue*ab  

* Corresponding authors

a State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

b Key Laboratory of Beijing City on Preparation and Processing of Novel Polymer Materials, Beijing 100029, China
E-mail: yuedm@mail.buct.edu.cn
Fax: +86-010-64436201
Tel: +86-010-64436201

Abstract

An Rh-based complex, T-Rh-PPh3, was developed through a facile one-step process. The T-Rh-PPh3 exhibited high activity and air stability in the hydrogenation of acrylonitrile–butadiene rubber. The enhanced air stability can be ascribed to the phenolic hydroxyl structures in tannin.

Graphical abstract: A ternary Rh complex catalyst highly active and stable in the hydrogenation of acrylonitrile–butadiene rubber

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Article information

DOI
https://doi.org/10.1039/C4NJ01627K
Article type
Letter
Submitted
21 Sep 2014
Accepted
22 Dec 2014
First published
23 Dec 2014

New J. Chem., 2015,39, 1583-1586

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A ternary Rh complex catalyst highly active and stable in the hydrogenation of acrylonitrile–butadiene rubber

P. Cao, M. Wu, R. Zou, L. Zhang and D. Yue, New J. Chem., 2015, 39, 1583 DOI: 10.1039/C4NJ01627K

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