Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 4, 2015
Previous Article Next Article

Photochemical recycling of europium from Eu/Y mixtures in red lamp phosphor waste streams

Author affiliations

Abstract

Europium is one of the most critical rare-earth elements due to the combination of a high demand for the production of red lamp phosphors and the limited supply of this element. Hence, the recycling of europium from end-of-life lamp phosphors has gained a lot of interest. Separation of europium from rare-earth mixtures can be done very efficiently by selective reduction of Eu(III) to Eu(II) and subsequent removal of Eu(II) by EuSO4 precipitation. The present study shows that full separation of europium from non-equimolar binary europium/yttrium mixtures, which reflect the rare earth composition of red lamp phosphors, can be achieved by photochemical reduction of Eu(III). Eu/Y molar ratios up to 1/20 were tested in the presence of an isopropanol radical scavenger, a less harmful and toxic compound than the commonly used formic acid scavenger. Moreover, in contrast to using the very acidic formic acid, higher pH values could be reached with isopropanol, which is advantageous for the formation and the stability of the reduced Eu(II) species. Faster europium removal was obtained at higher pH values up to pH 4, halving the illumination time to reach 88% of europium recovery. Efficiencies of over 95% were reached, with purities of 98.5% of the EuSO4 precipitate. Europium recovery of industrial YOX powder was also achieved from a Eu/Y 1/30 ratio, with 50% yield of EuSO4 and a purity of 96%.

Graphical abstract: Photochemical recycling of europium from Eu/Y mixtures in red lamp phosphor waste streams

Back to tab navigation
Please wait while Download options loads

Publication details

The article was received on 03 Nov 2014, accepted on 06 Jan 2015 and first published on 07 Jan 2015


Article type: Paper
DOI: 10.1039/C4GC02140A
Citation: Green Chem., 2015,17, 2180-2187
  •   Request permissions

    Photochemical recycling of europium from Eu/Y mixtures in red lamp phosphor waste streams

    B. Van den Bogaert, D. Havaux, K. Binnemans and T. Van Gerven, Green Chem., 2015, 17, 2180
    DOI: 10.1039/C4GC02140A

Search articles by author