Jump to main content
Jump to site search

Issue 8, 2015
Previous Article Next Article

Achieving overall water splitting using titanium dioxide-based photocatalysts of different phases

Author affiliations

Abstract

Titanium dioxide (TiO2) is regarded as the benchmark semiconductor in photocatalysis, which possesses a suitable band structure and makes the overall water splitting reaction thermodynamically possible. However, photocatalytic overall water splitting (POWS) (2H2O → 2H2 + O2) can only take place on rutile but hardly on anatase and brookite TiO2. So obtaining the POWS on TiO2-based photocatalysts has remained a long-standing challenge for over 40 years. In this work, we found that the POWS on anatase and brookite TiO2 becomes feasible under prolonged UV light irradiation. Further investigation by means of electron spin resonance spectroscopy (EPR) and transient infrared absorption–excitation energy scanning spectroscopy (TRIRA-ESS) reveals that both kinetics and thermodynamics factors contributed to unique POWS activity for different phases of TiO2. Kinetically the process of photocatalysis differs on different phases of TiO2 due to the intermediates (˙OH radical for anatase and brookite TiO2, peroxy species for rutile TiO2) that are formed. Thermodynamically there are many trapped states lying near the valence band of anatase and brookite but not for rutile TiO2, which reduce the overpotential for water oxidation. These findings develop our understanding of why some semiconductors are inactive as POWS photocatalysts despite having thermodynamically suitable band structures for the proton reduction and water oxidation reactions.

Graphical abstract: Achieving overall water splitting using titanium dioxide-based photocatalysts of different phases

Back to tab navigation

Supplementary files

Publication details

The article was received on 06 May 2015, accepted on 02 Jul 2015 and first published on 02 Jul 2015


Article type: Communication
DOI: 10.1039/C5EE01398D
Citation: Energy Environ. Sci., 2015,8, 2377-2382
  •   Request permissions

    Achieving overall water splitting using titanium dioxide-based photocatalysts of different phases

    R. Li, Y. Weng, X. Zhou, X. Wang, Y. Mi, R. Chong, H. Han and C. Li, Energy Environ. Sci., 2015, 8, 2377
    DOI: 10.1039/C5EE01398D

Search articles by author

Spotlight

Advertisements