Issue 43, 2015

Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

Abstract

A new 12-connected topological open-framework copper borovanadate NNU-6 with a unique B/V ratio (20/12) and a –B3O7(OH)–Na(μ-OH)[B(OH)2]–B3O7(OH)– connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest ratio of TM2+ and borovanadate anion, but also displays highly catalytic activities for the oxidation of benzyl-alkanes.

Graphical abstract: Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

Supplementary files

Article information

Article type
Communication
Submitted
03 Sep 2015
Accepted
02 Oct 2015
First published
07 Oct 2015

Dalton Trans., 2015,44, 18731-18736

Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

Y. Feng, C. Ding, H. Fan, Z. Zhong, D. Qiu and H. Shi, Dalton Trans., 2015, 44, 18731 DOI: 10.1039/C5DT03425F

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