Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)3 complexes

Patricia Gómez-Iglesias; Jose Miguel Martín-Alvarez; Daniel Miguel; Fernando Villafañe

doi:10.1039/C5DT03221K

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Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)₃ complexes†

Patricia Gómez-Iglesias,^a Jose Miguel Martín-Alvarez,^a Daniel Miguel^a and Fernando Villafañe*^a

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* Corresponding authors

^a GIR MIOMeT-IU Cinquima-Química Inorgánica, Facultad de Ciencias, Campus Miguel Delibes, Universidad de Valladolid, 47011 Valladolid, Spain
E-mail: fervilla@qi.uva.es

Abstract

The formation of an amidino chelating ligand from the coupling reaction of 1-methylcytosine and nitrile is a new method herein reported for the incorporation of biologically relevant substrates into rhenium(I) tricarbonyl complexes. The reactions are carried out thermally or are microwave assisted.

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Article information

DOI: https://doi.org/10.1039/C5DT03221K
Article type: Communication
Submitted: 20 Aug 2015
Accepted: 11 Sep 2015
First published: 16 Sep 2015

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Dalton Trans., 2015,44, 17478-17481

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Amidino ligands obtained from the coupling of 1-methylcytosine and nitrile: a new method to incorporate biomolecules into luminescent Re(CO)₃ complexes

P. Gómez-Iglesias, J. M. Martín-Alvarez, D. Miguel and F. Villafañe, Dalton Trans., 2015, 44, 17478 DOI: 10.1039/C5DT03221K

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Dalton Transactions