Jump to main content
Jump to site search

Issue 10, 2016
Previous Article Next Article

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Author affiliations

Abstract

A new member of the UiO-66 series of zirconium metal–organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon–carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Graphical abstract: Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Aug 2015, accepted on 11 Nov 2015 and first published on 11 Nov 2015


Article type: Communication
DOI: 10.1039/C5DT03178H
Citation: Dalton Trans., 2016,45, 4132-4135
  • Open access: Creative Commons BY license
  •   Request permissions

    Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

    R. J. Marshall, T. Richards, C. L. Hobday, C. F. Murphie, C. Wilson, S. A. Moggach, T. D. Bennett and R. S. Forgan, Dalton Trans., 2016, 45, 4132
    DOI: 10.1039/C5DT03178H

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements