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Issue 45, 2015
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Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

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Abstract

A new iron-catalyzed reaction for the coupling of perfluoroalkyl iodides (RFI) with aromatic substrates is described. The perfluoroalkylated arene products are obtained in good to excellent yields in the presence of a [(bpy)Fe(II)] catalyst (10%) electrochemically regenerated or generated from [(bpy)Fe(III)] at room temperature. The development, scope, and preliminary mechanistic studies of these transformations are reported.

Graphical abstract: Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

  • This article is part of the themed collection: Fluorine
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Publication details

The article was received on 05 Aug 2015, accepted on 30 Sep 2015 and first published on 30 Sep 2015


Article type: Paper
DOI: 10.1039/C5DT03009A
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 19674-19681
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    Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

    M. Khrizanforov, S. Strekalova, V. Khrizanforova, V. Grinenko, K. Kholin, M. Kadirov, T. Burganov, A. Gubaidullin, T. Gryaznova, O. Sinyashin, L. Xu, D. A. Vicic and Y. Budnikova, Dalton Trans., 2015, 44, 19674
    DOI: 10.1039/C5DT03009A

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