Issue 37, 2015
From the journal:

Dalton Transactions

Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates†

A. Ben Khélifa,a   M. Salah Belkhiria,a   G. Huang,b   S. Freslon,b   O. Guilloub  and  K. Bernot*b  

* Corresponding authors

a Laboratoire de Physico-chimie des Matériaux, Université de Monastir, Faculté des Sciences, Avenue de l'environnement, 5019 Monastir, Tunisia
E-mail: benkhelifaarbia@gmail.com

b INSA, UMR 6226, Institut des Sciences Chimiques de Rennes, 35708 Rennes, France
E-mail: Kevin.Bernot@insa-rennes.fr

Abstract

An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19]. The original electrostatic environment created around the CeIII by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.

Graphical abstract: Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

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Article information

DOI
https://doi.org/10.1039/C5DT02377G
Article type
Paper
Submitted
23 Jun 2015
Accepted
20 Jul 2015
First published
20 Jul 2015

Dalton Trans., 2015,44, 16458-16464

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Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates

A. B. Khélifa, M. S. Belkhiria, G. Huang, S. Freslon, O. Guillou and K. Bernot, Dalton Trans., 2015, 44, 16458 DOI: 10.1039/C5DT02377G

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