Issue 29, 2015

A water-soluble and water-coordinated Mn(ii) complex: synthesis, characterization and phantom MRI image study

Abstract

Ligand H4bedik was reacted with MnCl2·4H2O at pH ∼ 6.5 to give a highly water-soluble and water-coordinated Mn(II) complex (1). The complex was found to show r1 = 3.11 mM−1 s−1 per Mn(II) at 1.4 T and 6.26 mM−1 s−1 per Mn(II) at 14.1 T at 25 °C, pH = 7.4. In addition to r1, the r2 at 14.1 T was found to be 132.78 mM−1 s−1 per Mn(II) at 25 °C, pH = 7.4.

Graphical abstract: A water-soluble and water-coordinated Mn(ii) complex: synthesis, characterization and phantom MRI image study

Supplementary files

Article information

Article type
Communication
Submitted
12 May 2015
Accepted
05 Jun 2015
First published
05 Jun 2015

Dalton Trans., 2015,44, 12990-12994

A water-soluble and water-coordinated Mn(II) complex: synthesis, characterization and phantom MRI image study

B. Phukan, A. B. Patel and C. Mukherjee, Dalton Trans., 2015, 44, 12990 DOI: 10.1039/C5DT01781E

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