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Issue 45, 2015
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Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand

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Abstract

The [C4F8] ligand was shown to support well-defined terpyridyl nickel complexes in the +2 and +3 oxidation states. Notably, a cyclic voltammetry study of the nickel(III) species indicates that an additional oxidation is accessible, providing a family of related fluoroalkyl nickel complexes spanning the +2 to +4 oxidation states.

Graphical abstract: Accessing perfluoroalkyl nickel(ii), (iii), and (iv) complexes bearing a readily attached [C4F8] ligand

  • This article is part of the themed collection: Fluorine
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Publication details

The article was received on 11 May 2015, accepted on 05 Jun 2015 and first published on 05 Jun 2015


Article type: Communication
DOI: 10.1039/C5DT01771H
Citation: Dalton Trans., 2015,44, 19443-19446
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    Accessing perfluoroalkyl nickel(II), (III), and (IV) complexes bearing a readily attached [C4F8] ligand

    S. Yu, Y. Dudkina, H. Wang, K. V. Kholin, M. K. Kadirov, Y. H. Budnikova and D. A. Vicic, Dalton Trans., 2015, 44, 19443
    DOI: 10.1039/C5DT01771H

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