Issue 26, 2015
From the journal:

Dalton Transactions

How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning†

Màrius Tarrés,a   Víctor S. Arderiu,a   Adnana Zaulet,a   Clara Viñas,a   Fabrizia Fabrizi de Bianib  and  Francesc Teixidor*a  

* Corresponding authors

a Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus UAB, E-08193 Bellaterra, Spain
E-mail: teixidor@icmab.es

b Dipartimento di Biotecnologie, Chimica e Farmacia, UniversitàdegliStudi di Siena, Via A. Moro 2, 53100 Siena, Italy

Abstract

An appealingly wide set of redox couples ranging from −1.74 to −0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11−yIy)2]− (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV]2+) has been used as a benchmark.

Graphical abstract: How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5DT01464F
Article type
Communication
Submitted
17 Apr 2015
Accepted
22 May 2015
First published
22 May 2015

Dalton Trans., 2015,44, 11690-11695

Author version available

Download author version (PDF)

Permissions

Request permissions

How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning

M. Tarrés, V. S. Arderiu, A. Zaulet, C. Viñas, F. Fabrizi de Biani and F. Teixidor, Dalton Trans., 2015, 44, 11690 DOI: 10.1039/C5DT01464F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements