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Issue 20, 2015
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Aminobisphenolate supported tungsten disulphido and dithiolene complexes

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Abstract

Dioxotungsten(VI) complexes with tetradentate amino bisphenolates were converted into the corresponding Cs-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(IV) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented.

Graphical abstract: Aminobisphenolate supported tungsten disulphido and dithiolene complexes

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Publication details

The article was received on 12 Mar 2015, accepted on 17 Apr 2015 and first published on 21 Apr 2015


Article type: Paper
DOI: 10.1039/C5DT00995B
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 9409-9416
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    Aminobisphenolate supported tungsten disulphido and dithiolene complexes

    E. Salojärvi, A. Peuronen, R. Sillanpää, P. Damlin, H. Kivelä and A. Lehtonen, Dalton Trans., 2015, 44, 9409
    DOI: 10.1039/C5DT00995B

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