Issue 17, 2015
From the journal:

Dalton Transactions

From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors†

Javier Pitarch-Jarque,a   Raquel Belda,a   Laura García-España,a   José M. Llinares,b   FangFang Pan,c   Kari Rissanen,c   Pilar Navarrod  and  Enrique García-España*a  

* Corresponding authors

a Instituto de Ciencia Molecular, Universidad de Valencia, C/Catedrático José Beltrán 2, Paterna, Spain
E-mail: enrique.garcia-es@uv.es

b Departamento de Química Orgánica, Instituto de Ciencia Molecular, Universidad de Valencia, C/Catedrático José Beltrán 2, Paterna, Spain

c University of Jyvaskyla, Department of Chemistry, Nanoscience Center, P.O. Box. 35, FI-40014, Finland

d Instituto de Química Médica, CSIC. C/Juan de la Cierva 3, Madrid, Spain

Abstract

We report a novel 1-D helical coordination polymer formed by protonated polyamine 1H-pyrazole cryptands interconnected by Cu2+ metal ions that are able to encapsulate anionic species behaving as a multianion receptor. Switching from a monomeric receptor to a polymeric receptor is activated by metal ions and pH.

Graphical abstract: From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors

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Article information

DOI
https://doi.org/10.1039/C5DT00763A
Article type
Communication
Submitted
21 Feb 2015
Accepted
25 Mar 2015
First published
25 Mar 2015

Dalton Trans., 2015,44, 7761-7764

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From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors

J. Pitarch-Jarque, R. Belda, L. García-España, J. M. Llinares, F. Pan, K. Rissanen, P. Navarro and E. García-España, Dalton Trans., 2015, 44, 7761 DOI: 10.1039/C5DT00763A

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