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Issue 19, 2015
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Nanoheterogeneous catalysis in electrochemically induced olefin perfluoroalkylation

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Abstract

Ni-catalyzed electroreductive olefin perfluoroalkylation affords both monomeric and dimeric products depending on the reaction media. Recycling of the catalyst can be achieved by immobilization of a (bpy)NiBr2 complex on silica nanoparticles decorated with anchoring amino-groups. Switching the homogeneous and heterogeneous catalysts is found to be one more factor to control the product ratio. This catalytic technique is both green and atom economical and combines the advantages of nanoheterogeneous catalysis and electrocatalysis.

Graphical abstract: Nanoheterogeneous catalysis in electrochemically induced olefin perfluoroalkylation

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Publication details

The article was received on 20 Jan 2015, accepted on 30 Mar 2015 and first published on 01 Apr 2015


Article type: Paper
DOI: 10.1039/C5DT00269A
Author version available: Download Author version (PDF)
Citation: Dalton Trans., 2015,44, 8833-8838
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    Nanoheterogeneous catalysis in electrochemically induced olefin perfluoroalkylation

    Y. B. Dudkina, T. V. Gryaznova, Y. N. Osin, V. V. Salnikov, N. A. Davydov, S. V. Fedorenko, A. R. Mustafina, D. A. Vicic, O. G. Sinyashin and Y. H. Budnikova, Dalton Trans., 2015, 44, 8833
    DOI: 10.1039/C5DT00269A

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